I have no experience with OMV specifically, but generally making things accessible from outside your house means exposing it ti the internet.
However, what you can do is to only expose an openvpn port, so that to gain access as if you were at home you could connect via o0envpn first.
No, just one. You set up one device/server as a VPN gateway (often called VPN concentrator), and you will have access to anything the concentrator has access to on your home network.
Either you just your VPN concentrator as your jump box, or you set up routing and firewalls to be able to access them directly.